Metal ion-binding properties of L-glutamic acid and L-aspartic acid, a comparative investigation

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Metal ion-binding properties of L-glutamic acid and L-aspartic acid, a comparative investigation

A comparative research has been developed for acidity and stability constants of M(Glu), M(Asp) and M(Ttr) complexes, which have been determined by potentiometric pH titration. Depending on metal ion-binding properties, vital differences in building complex were observed. The present study indicates that in M(Ttr) complexes, metal ions are arranged to the carboxyl groups, but in M(Glu) and M(As...

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Metal ion–binding properties of the L-aspartic acid and tartaric acid, a coparative investigation. How can be increased the dosage of mineral absorption in the body

A comparative research has been developed for acidity and stability constants of M(TTA) and M(Asp) complexes which have been determined by potentiometric pH titration. Depending on metal ion–binding properties, vital differences in building complex were observed. The present study shows that in M(TTA) complexes, metal ions are coordinated to the carboxyl groups, but in M(Asp) some metal ions ar...

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Metabolism of L-aspartic acid.

Aspartic acid, like glutamic acid, occupies a central position in amino acid metabolism. In most tissues it takes part in the transamination reaction (1). In the liver and the kidney, where all amino acids undergo cleamination, the rate of this process for aspartic acid is second only to glutamic acid (2). For these reasons, one would expect the exchange of amino nitrogen of aspartic acid with ...

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A route to anionic hydrophilic films of copolymers of L-leucine, L-aspartic acid and L-aspartic acid esters

A series of copolymers of L-leucine and/3-benzyI-L-aspartate [Leu/Asp(OBz)] covering the range 30-70 mol % of L-leucine, was synthesized by the N-carboxyanhydride (NCA) method. The copolymers were characterized by elemental analysis, infra-red spectroscopy and viscometry. For all compositions high molecular weight copolymers were prepared with excellent film-forming properties. Tercopolymers of...

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Oxovanadium(IV) complexes of salicyl-L-aspartic acid and salicylglycyl-L-aspartic acid.

The dipeptide and tripeptide analogues salicyl-L-aspartic acid (Sal-L-Asp) and salicylglycyl-L-aspartic acid (SalGly-L-Asp) were synthesized and their protonation and complex formation with V(IV)O2+ were studied in aqueous solution through the use of pH-potentiometry and spectroscopic (UV-Vis, CD and EPR) techniques. The phenolate terminus proved to be a good anchoring site to promote (i) the m...

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ژورنال

عنوان ژورنال: Natural Science

سال: 2010

ISSN: 2150-4091,2150-4105

DOI: 10.4236/ns.2010.22013